HuagongsheHuagongshe Chemistry Print Report · For research reference only
Trifluoroacetic acid → Cyclohexyl trifluoroacetate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Trifluoroacetic acid | HCID 6422 | — |
| Reactant | Cyclohexene | HCID 8079 | — |
| Catalyst | Copper | HCID 23978 | — |
| Product | Cyclohexyl trifluoroacetate | HCID 519124 | — |
Reaction Steps
Both experiments with copper metal deposited the white precipitate. During the course of the second experiment, solution samples were taken for analysis. Cyclohexene was found to be the major reaction product (ester/olefin=0.2) which slowly reacted with trifluoroacetic acid to form cyclohexyltrifluoroacetate. Thus, elimination of cyclohexene from a cyclohexyl-copper complex is the predominant reaction pathway under our conditions.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05786505 |
| Source dataset | uspto-grants-1998_07 |
| ORD ID | ord-de95a33ad53647608ff14e284614b40a |
| Source note | uspto-grants-1998_07 |