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HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1957768Generated: November 2, 2026

Trifluoroacetic acid → Cyclohexyl trifluoroacetate

https://huagongshe.com/reaction/1957768

Reaction equation

Participants

RoleNameHCIDCharge
ReactantTrifluoroacetic acidHCID 6422—
ReactantCyclohexeneHCID 8079—
CatalystCopperHCID 23978—
ProductCyclohexyl trifluoroacetateHCID 519124—

Reaction Steps

Both experiments with copper metal deposited the white precipitate. During the course of the second experiment, solution samples were taken for analysis. Cyclohexene was found to be the major reaction product (ester/olefin=0.2) which slowly reacted with trifluoroacetic acid to form cyclohexyltrifluoroacetate. Thus, elimination of cyclohexene from a cyclohexyl-copper complex is the predominant reaction pathway under our conditions.

Provenance & Evidence

DOI10.6084/m9.figshare.5104873.v1
Patent numberUS05786505
Source datasetuspto-grants-1998_07
ORD IDord-de95a33ad53647608ff14e284614b40a
Source noteuspto-grants-1998_07