HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyltrimethylsilane → ((3-(Hexyloxy)phenyl)ethynyl)trimethylsilane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyltrimethylsilane | HCID 137936 | — |
| Reactant | 1-Bromo-3-(heptyloxy)benzene | HCID 43129477 | — |
| Product | ((3-(Hexyloxy)phenyl)ethynyl)trimethylsilane | HCID 68743503 | 55% |
Reaction Steps
According to the method described in Example S117a, 1-bromo-3-(heptyloxy)benzene (1 g, 4 mmol) was reacted with trimethylsilylethane (0.43 g, 4.4 mmol) to give the title compound as a yellow oil (575 mg, 55%). 1H NMR (400 MHz, CDCl3) δ 7.19 (t, 1H, J=7.6 Hz), 7.05 (d, 1H, J=7.2 Hz), 6.99 (s, 1H), 6.87 (d, 1H, J=7.0 Hz), 3.94 (t, 2H, J=6.8 Hz), 1.79-1.75 (m, 2H), 1.47-1.30 (m, 6H), 0.91 (t, 3H, J=6.8 Hz), 0.26 (s, 9H).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US08410150B2 |
| Source dataset | uspto-grants-2013_04 |
| ORD ID | ord-1826ae534ca54637b4b9ca3386c0d43a |
| Source note | uspto-grants-2013_04 |