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Dimethyl Sulfoxide → 1,1'-Disulfanediylbis(2-chlorobenzene)
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dimethyl Sulfoxide | HCID 679 | — |
| 反応物 | Hexamethyldisilazane | HCID 13838 | — |
| 反応物 | o-Chlorothiophenol | HCID 80599 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 生成物 | 1,1'-Disulfanediylbis(2-chlorobenzene) | HCID 233482 | — |
反応手順
Hexamethyldisilazane (4.4 ml) was added to a stirred solution of 2-chlorobenzenethiol (2.0 ml) and DMSO (3.7 ml) in dry acetonitrile at room temperature. After 2 h the white precipitate was filtered and washed (cold acetonitrile) to give the sub-title compound as a white solid (2.27 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08415394B2 |
| 出典データセット | uspto-grants-2013_04 |
| ORD ID | ord-e8d37b29b0a04cc6a9a7475fed1a8408 |
| 出典メモ | uspto-grants-2013_04 |