Benzene, 1-(bromomethyl)-3-nitro- → HCID 66877414, compound

HRID 1964034Notes

Reaction equation

HRID 1964034 reaction equation
[O:1]1[CH:5]=[CH:4][CH:3]=[C:2]1B(O)O.[N+:9]([C:12]1[CH:13]=[C:14]([CH:17]=[CH:18][CH:19]=1)[CH2:15]Br)([O-:11])=[O:10]>>[N+:9]([C:12]1[CH:13]=[C:14]([CH:17]=[CH:18][CH:19]=1)[CH2:15][C:2]1[O:1][CH:5]=[CH:4][CH:3]=1)([O-:11])=[O:10]

Participants

3

Reactant 2

HCID 77568Benzene, 1-(bromomethyl)-3-nitro-HCID 2734357Furan-2-boronic acid

Product 1

HCID 66877414HCID 66877414, compoundYield 92%

Procedure

Using the same method as in Example 19-(ii), 2-furanboronic acid was reacted with the 3-nitrobenzyl bromide to give 2-(3-nitrobenzyl)furan (yield: 92%).

Sources & evidence

ORD record
ord-5306a96115df4c5b91dbdd384d0e6201
Source dataset
uspto-grants-2013_04
Patent number
US08415479B2

Reaction notes

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