Benzene, 1-(bromomethyl)-3-nitro- → HCID 66877412, compound

HRID 1964037Notes

Reaction equation

HRID 1964037 reaction equation
[O:1]1[CH:5]=[CH:4][C:3](B(O)O)=[CH:2]1.[N+:9]([C:12]1[CH:13]=[C:14]([CH:17]=[CH:18][CH:19]=1)[CH2:15]Br)([O-:11])=[O:10]>>[N+:9]([C:12]1[CH:13]=[C:14]([CH:17]=[CH:18][CH:19]=1)[CH2:15][C:3]1[CH:4]=[CH:5][O:1][CH:2]=1)([O-:11])=[O:10]

Participants

3

Reactant 2

HCID 77568Benzene, 1-(bromomethyl)-3-nitro-HCID 2734358Furan-3-boronic acid

Product 1

HCID 66877412HCID 66877412, compoundYield 84%

Procedure

Using the same method as in Example 19-(ii), 3-furanboronic acid was reacted with the 3-nitrobenzyl bromide to give 3-(3-nitrobenzyl)furan (yield: 84%).

Sources & evidence

ORD record
ord-4b7ac9af0a49431aa8af53523c3942b9
Source dataset
uspto-grants-2013_04
Patent number
US08415479B2

Reaction notes

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