Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
Dichloromethane → Dimethyl 1,4-cyclohexanedicarboxylate
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|---|---|---|
| 반응물 | Dichloromethane | HCID 6344 | — |
| 반응물 | Dimethyl cyclohex-1-ene-1,4-dicarboxylate | HCID 13633969 | — |
| 반응물 | Dimethyl cyclohex-2-ene-1,4-dicarboxylate | HCID 59071935 | — |
| 촉매 | Palladium | HCID 23938 | — |
| 용매 | Ethanol | HCID 702 | — |
| 생성물 | Dimethyl 1,4-cyclohexanedicarboxylate | HCID 7198 | — |
반응 단계
A solution of dimethyl cyclohex-2-ene-1,4-dicarboxylate and dimethyl cyclohex-1-ene-1,4-dicarboxylate is hydrogenated under balloon pressure at room temperature over Pd/C catalyst. If methylene chloride is used as the solvent, primarily the 2-ene tautomer is reduced, whereas most of the 1-ene tautomer remains unreacted. If ethanol is used as the solvent both tautomers are reduced.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 특허 번호 | US08415496B2 |
| 출처 데이터셋 | uspto-grants-2013_04 |
| ORD ID | ord-31a3476671214f478d32003c25dc2100 |
| 출처 메모 | uspto-grants-2013_04 |