2-Chloro-3,5-dinitropyridine → HCID 86643268, compound

HRID 1967472Notes

Reaction equation

HRID 1967472 reaction equation
Cl[C:2]1[C:7]([N+:8]([O-:10])=[O:9])=[CH:6][C:5]([N+:11]([O-:13])=[O:12])=[CH:4][N:3]=1.[NH2:14][CH2:15][CH2:16][CH:17]([C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1)[C:18]([O:20][CH3:21])=[O:19]>>[N+:8]([C:7]1[C:2]([NH:14][CH2:15][CH2:16][CH:17]([C:22]2[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=2)[C:18]([O:20][CH3:21])=[O:19])=[N:3][CH:4]=[C:5]([N+:11]([O-:13])=[O:12])[CH:6]=1)([O-:10])=[O:9]

Participants

3

Reactant 2

HCID 757382-Chloro-3,5-dinitropyridineHCID 57302683HCID 57302683, compound

Product 1

HCID 86643268HCID 86643268, compoundYield 77.7%

Procedure

A procedure similar to the method described in step C.1 is carried out, starting from 0.8 g (3.93 mmol) of 2-chloro-3,5-dinitropyridine and 1 g (4.32 mmol) of methyl 4-amino-2-phenylbutyrate. This gives 1.1 g of expected product.

Sources & evidence

ORD record
ord-b9cf20ad6b6d4e1187802a4eead8d0c4
Source dataset
uspto-grants-2013_04
Patent number
US08420817B2

Reaction notes

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