HuagongsheHuagongshe Chemistry Print Report · For research reference only
Butanal → HCID 86734240, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Butanal | HCID 261 | — |
| Reactant | Propylene | HCID 8252 | — |
| Reactant | 2-Hexene | HCID 19966 | — |
| Product | HCID 86734240 | HCID 86734240 | — |
Reaction Steps
The above data confirm that after the initial selective or preferential hydroformylation of the 1-alkene (propene) fraction to n-butyraldehyde is essentially complete (>95% conversion after about 6 hours), the remaining 2-hexene fraction may be hydroformylated to iso-heptaldehydes using the same catalyst solution and the same reaction conditions. In this way, the complex PtCl2 [P(C6H5)3 ]2 -SnCl2 allows sequential hydroformylation of the α-olefin-internal olefin mixture of propene and 2-hexene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03996293 |
| Source dataset | uspto-grants-1976_12 |
| ORD ID | ord-35d34a9fd4134cf495680c205681287f |
| Source note | uspto-grants-1976_12 |