HuagongsheHuagongshe Chemistry Print Report · For research reference only
Ethyl Acetoacetate → N-(12-Acetyl-12-Carboethoxydodecanoyl)morpholine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Ethyl Acetoacetate | HCID 8868 | — |
| Reactant | N-10-Undecenoylmorpholine | HCID 96360 | — |
| Catalyst | Cobalt-60 | HCID 61492 | — |
| Product | N-(12-Acetyl-12-Carboethoxydodecanoyl)morpholine | HCID 21453509 | — |
Reaction Steps
Samples of 2 grams (.0078 mole) of 10-undecenoylmorpholine and 30.9 grams (0.237 mole) of ethyl acetoacetate were placed in a flask, mixed well, and exposed to a cobalt-60 (γ-radiation) source to initiate free radical chain reaction. After irradiating for 17 hours, the mixture was removed from the irradiation source and stripped under reduced pressure. Analysis of the product, N-(12-acetyl-12-carboethoxydodecanoyl) morpholine: % G 65.78 (theory 65.76); % H, 9.87 (theory 9.73); % N, 3.68 (theory 3.65).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03996353 |
| Source dataset | uspto-grants-1976_12 |
| ORD ID | ord-60565c1980b141f7bc92b1d591cb2f78 |
| Source note | uspto-grants-1976_12 |