HuagongsheHuagongshe Chemistry Print Report · For research reference only
Benzoyl chloride → {3-Methyl-2-[nitro(phenylsulfanyl)methylidene]imidazolidin-1-yl}(phenyl)methanone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Benzoyl chloride | HCID 7412 | — |
| Reactant | Triethylamine | HCID 8471 | — |
| Reactant | 1-Methyl-2-[nitro(phenylsulfanyl)methylidene]imidazolidine | HCID 70639009 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | {3-Methyl-2-[nitro(phenylsulfanyl)methylidene]imidazolidin-1-yl}(phenyl)methanone | HCID 54537871 | — |
Reaction Steps
0.71 g of benzoyl chloride was added to 1.26 g of 1B and 0.63 g of triethylamine in 25 ml of methylene chloride at 0°-20°. After stirring overnight at room temperature, the solvent was stripped. The solid residue was triturated with ice-cold methanol and then filtered to give 2, as a yellow solid, m.p.: 175°-178°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03996372 |
| Source dataset | uspto-grants-1976_12 |
| ORD ID | ord-283fd835c1c544ffb04fed3235478541 |
| Source note | uspto-grants-1976_12 |