HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Chloro-2-butanone → 2,5,6-Trimethyl-2,3-dihydro-1,4-dithiine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Chloro-2-butanone | HCID 20026 | — |
| Reactant | 2,3-Dimercaptopropane | HCID 61217 | — |
| Product | 2,5,6-Trimethyl-2,3-dihydro-1,4-dithiine | HCID 12920048 | 36.5% |
Reaction Steps
The procedure of Example 1(a) is repeated, using 1,2-propanedithiol and 3-chloro-2-butanone to give 2,3-dihydro-2,5,6-trimethyl-1,4-dithiin as a clear green liquid, bp 49.5°-51°/0.7 mm, yield 36.5% NMR 1.36 (3d), 1.88 (6s), 2.4-3.6 (3m) (CDCl3). IR, 2905 (sh); 1605, 1410 (broad); 1250, 1155 (sh); 1065 (br); 730, 705.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03997323 |
| Source dataset | uspto-grants-1976_12 |
| ORD ID | ord-2d4f7479fab149d8a85cc024eb4535d9 |
| Source note | uspto-grants-1976_12 |