HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Chloro-2-butanone → 2-Ethyl-5,6-dimethyl-2,3-dihydro-1,4-dithiine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Chloro-2-butanone | HCID 20026 | — |
| Reactant | 1,2-Butanedithiol | HCID 61829 | — |
| Product | 2-Ethyl-5,6-dimethyl-2,3-dihydro-1,4-dithiine | HCID 12920051 | 35% |
Reaction Steps
The procedure of Example 1(a) is repeated, using 1,2-butanedithiol and 3-chloro-2-butanone to give 2-ethyl-2,3-dihydro-5,6-dimethyl-1,4-dithiin as a colorless oil, bp 68°-81°/0.7, yield 35%, NMR 1.01 (3t), 1.4-2.9 (2m), 1.87 (6s), 2.6-3.4 (3m). IR, 2910 (sh); 1610 (sh); 1410, 1220 (sh); 1155 (sh); 1070, 735, 700.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03997323 |
| Source dataset | uspto-grants-1976_12 |
| ORD ID | ord-a82a423eab324df28ddba254b8ee7c95 |
| Source note | uspto-grants-1976_12 |