HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Chlorocyclohexanone → 2,3-Dimethyl-2,3,5,6,7,8-hexahydro-1,4-benzodithiine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Chlorocyclohexanone | HCID 13203 | — |
| Reactant | 2,3-Butanedithiol | HCID 548353 | — |
| Product | 2,3-Dimethyl-2,3,5,6,7,8-hexahydro-1,4-benzodithiine | HCID 12920054 | 49% |
Reaction Steps
The procedure of Example 1(a) is followed using 2,3-butanedithiol and 2-chlorocyclohexanone to give 5,6,7,8-tetrahydro-2,3-dimethyl-1,4-benzodithian as a greenish oil, b.p. 90°-100°/0.07 mm. Yield 49%. NMR 1.34 (6d), 1.45-2.25 (8m), 2.7-3.1 (2m). IR 2900, 1610, 1435, 1365, 1320, 1115, 795, 690.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03997323 |
| Source dataset | uspto-grants-1976_12 |
| ORD ID | ord-8056b03b1f3c4fac88325a493db41bbe |
| Source note | uspto-grants-1976_12 |