HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Hydroxide → (2E)-N-(3,4-Dichlorophenyl)-2H-quinolizin-2-imine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | Nolinium Bromide | HCID 38666 | — |
| Solvent | Water | HCID 962 | — |
| Product | (2E)-N-(3,4-Dichlorophenyl)-2H-quinolizin-2-imine | HCID 330198 | — |
Reaction Steps
A solution of 2-(3,4-dichloroanilino)quinolizinium bromide (23 g, 0.062 mole) in water (1 l.) was warmed to 50°. The warm solution was stirred and treated with a 2 N solution of NaOH (400 ml). The solution precipitated a yellow-orange product and the aqueous solution was warmed at 50° for 1 hour. After cooling and filtration the air dried product weighed 18 g (100%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US03997547 |
| Source dataset | uspto-grants-1976_12 |
| ORD ID | ord-d81eaf1f31c94ff881587183744e14ab |
| Source note | uspto-grants-1976_12 |