p-Toluenesulfonyl isocyanate → HCID 20325605, compound

HRID 1973752Notes

Reaction equation

HRID 1973752 reaction equation
[C:1]([CH:5]1[CH2:10][C:9](=[O:11])[CH2:8][C:7](=[O:12])[CH2:6]1)([CH3:4])([CH3:3])[CH3:2].[C:13]1([CH3:25])[CH:18]=[CH:17][C:16]([S:19]([N:22]=[C:23]=[O:24])(=[O:21])=[O:20])=[CH:15][CH:14]=1>C1C=CC=CC=1>[C:1]([CH:5]1[CH2:6][C:7](=[O:12])[CH:8]([C:23](=[O:24])[NH:22][S:19]([C:16]2[CH:17]=[CH:18][C:13]([CH3:25])=[CH:14][CH:15]=2)(=[O:20])=[O:21])[C:9](=[O:11])[CH2:10]1)([CH3:4])([CH3:2])[CH3:3]

Participants

4

Reactant 2

HCID 77703p-Toluenesulfonyl isocyanateHCID 20325608HCID 20325608, compound

Product 1

HCID 20325605HCID 20325605, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

Reaction of 5-tert.-butyl-1,3-cyclohexanedione with p-toluenesulfonylisocyanate in benzene according to the procedure of Example 1 affords 5-tert.-BUTYL-2-(N-p-TOLUENESULFONYLCARBAMOYL)-1,3-CYCLOHEXANEDIONE, m.p. 161.5°-163° C. (corr.).

Sources & evidence

ORD record
ord-dfdc1ee69c2c4bccb854894f4ca7b6c3
Source dataset
uspto-grants-1976_12
Patent number
US03998879

Reaction notes

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