Phenyl isocyanate → HCID 3039359, compound

HRID 1973920Notes

Reaction equation

HRID 1973920 reaction equation
[NH:1]=[C:2]1[CH2:6][CH2:5][CH2:4][N:3]1[CH3:7].[C:8]1([N:14]=[C:15]=[O:16])[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1>C1C=CC=CC=1>[CH3:7][N:3]1[CH2:4][CH2:5][CH2:6][C:2]1=[N:1][C:15]([NH:14][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)=[O:16]

Participants

4

Reactant 2

HCID 7672Phenyl isocyanateHCID 124489661-Methyl-2-pyrrolidinimine

Product 1

HCID 3039359HCID 3039359, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

After dissolving 4.9 g. (0.05 mole) of 2 -imino-1 -methylpyrrolidine in anhydrous benzene, 5.96 g. (0.05 mole) of phenylisocyanate is added dropwise with stirring (heat evolves). The reaction mixture is stirred for one-half hour. The solid product which is formed, 1 -(1 -methyl-2 -pyrrolidylidene)-3 -phenylurea, is collected (m.p. = 140-144° C.); recrystallized from methanol to give the pure product, m.p. = 146-147.5° C.

Workup

  1. dissolutionAfter dissolving 4.9 g
  2. temperature(heat evolves)
  3. stirringThe reaction mixture is stirred for one-half hour
  4. customThe solid product which is formed
  5. custom1 -(1 -methyl-2 -pyrrolidylidene)-3 -phenylurea, is collected (m.p. = 140-144° C.)
  6. customrecrystallized from methanol
  7. customto give the pure product, m.p. = 146-147.5° C.

Sources & evidence

ORD record
ord-9e94d4a1b7d64f47af4e31900eee6645
Source dataset
uspto-grants-1976_12
Patent number
US03998958

Reaction notes

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