O-Allylhydroxylamine → HCID 178460159, compound

HRID 1974000Notes

Reaction equation

HRID 1974000 reaction equation
[C:1]([CH:6]1[C:11](=[O:12])[N:10]([CH3:13])[C:9](=[O:14])[N:8]([CH3:15])[C:7]1=[O:16])(=O)[CH2:2][CH2:3][CH3:4].[CH2:17]([O:20][NH2:21])[CH:18]=[CH2:19]>C(O)C>[CH2:17]([O:20][NH:21][C:1](=[C:6]1[C:11](=[O:12])[N:10]([CH3:13])[C:9](=[O:14])[N:8]([CH3:15])[C:7]1=[O:16])[CH2:2][CH2:3][CH3:4])[CH:18]=[CH2:19]

Participants

4

Reactant 2

HCID 420841O-AllylhydroxylamineHCID 21488152HCID 21488152, compound

Product 1

HCID 178460159HCID 178460159, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent2×

Procedure

2.3 g of 5-butyryl-1,3-dimethylbarbituric acid was dissolved in 30 ml of ethanol and 1 g of allyloxyamine was added to it at a temperature of 30° C. After stirring during 2 hours, said ethanol was distilled off and thereby 2.6 g of white crystals was separated. The purified compound was obtained as needles by recrystallization from methanol.

Workup

  1. distillationwas distilled off
  2. custom2.6 g of white crystals was separated
  3. customThe purified compound was obtained as needles by recrystallization from methanol

Sources & evidence

ORD record
ord-a7d5e157419449d3a4d9a8cc81631ad1
Source dataset
uspto-grants-1976_12
Patent number
US03999974

Reaction notes

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