2,6-Di-tert-pentylphenol → 2,5-Bis(3,5-di-tert-amyl-4-hydroxyphenyl)-9-thiabicyclo[4.2.1]nonane

HRID 1974015Notes

Reaction equation

HRID 1974015 reaction equation
[C:1]([C:9]1[CH:10]=[C:11]([CH:24]2[CH2:31][CH2:30][CH:29]([C:32]3[CH:37]=[C:36]([C:38]([CH2:41][C:42](C)(C)C)([CH3:40])[CH3:39])[C:35]([OH:46])=[C:34]([C:47]([CH2:50][C:51](C)(C)C)([CH3:49])[CH3:48])[CH:33]=3)[CH:28]3[S:55][CH:25]2[CH2:26][CH2:27]3)[CH:12]=[C:13]([C:16]([CH2:19][C:20](C)(C)C)([CH3:18])[CH3:17])[C:14]=1[OH:15])([CH2:4][C:5](C)(C)C)([CH3:3])[CH3:2].C(C1C=CC=C(C(CC)(C)C)C=1O)(CC)(C)C.C(C1C=C(C2CCC3SC2CCC3C2C=C(C(CC)(C)C)C(O)=C(C(CC)(C)C)C=2)C=C(C(CC)(C)C)C=1O)(CC)(C)C>>[C:16]([C:13]1[CH:12]=[C:11]([CH:24]2[CH2:31][CH2:30][CH:29]([C:32]3[CH:37]=[C:36]([C:38]([CH2:41][CH3:42])([CH3:40])[CH3:39])[C:35]([OH:46])=[C:34]([C:47]([CH2:50][CH3:51])([CH3:48])[CH3:49])[CH:33]=3)[CH:28]3[S:55][CH:25]2[CH2:26][CH2:27]3)[CH:10]=[C:9]([C:1]([CH2:4][CH3:5])([CH3:2])[CH3:3])[C:14]=1[OH:15])([CH2:19][CH3:20])([CH3:17])[CH3:18]

Participants

4

Reactant 3

HCID 144965062,6-Di-tert-pentylphenolHCID 21488256HCID 21488256, compoundHCID 21488267HCID 21488267, compound

Product 1

HCID 214882602,5-Bis(3,5-di-tert-amyl-4-hydroxyphenyl)-9-thiabicyclo[4.2.1]nonane

Procedure

When in Example 1, the 2,6-di-tert-butylphenol is replaced by an equivalent amount of 2,6-di-tert-amylphenol, a mixture of 2,6-bis(3,5-di-tert-amyl-4-hydroxyphenyl)-9-thiabicyclo[3.3.1]nonane and 2,5-bis(3,5-di-tert-amyl-4-hydroxyphenyl)-9-thiabicyclo[4.2.1]nonane is obtained.

Sources & evidence

ORD record
ord-6b5bbb4909e2472b82facc66b88899f8
Source dataset
uspto-grants-1976_12
Patent number
US04000112

Reaction notes

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