HCID 21488582, compound → HCID 21488578, compound

HRID 1974065Notes

Reaction equation

HRID 1974065 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]2[C:11](=[CH:12][CH:13]=1)[N:10]1[C:14](C)=[N:15][N:16]=[C:9]1[CH:8]=[C:7]2[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][C:19]=1[Cl:24])([O-:3])=[O:2].I([O-])(=O)(=O)=[O:26].[Na+]>[Ru](=O)=O>[Cl:24][C:19]1[CH:20]=[CH:21][CH:22]=[CH:23][C:18]=1[C:7](=[O:26])[C:6]1[CH:5]=[C:4]([N+:1]([O-:3])=[O:2])[CH:13]=[CH:12][C:11]=1[N:10]1[CH:14]=[N:15][N:16]=[C:9]1[CH3:8]

Participants

4

Reactant 2

HCID 21488582HCID 21488582, compoundHCID 23667635Sodium periodate

Product 1

HCID 21488578HCID 21488578, compound

Reagents, catalysts & solvents 1

HCID 82848Ruthenium dioxideCatalyst

Procedure

In the manner given in Example 3, 7-nitro-1-methyl-5-(o-chlorophenyl)-s-triazolo[4,3-a]quinoline is oxidized at low temperature with sodium periodate and ruthenium dioxide to give 2'-chloro-5-nitro-2-(3-methyl-4H-1,2,4-triazol-4-yl)benzophenone.

Sources & evidence

ORD record
ord-c1a5a30ed5024ea08ca48d8832671243
Source dataset
uspto-grants-1976_12
Patent number
US04000151

Reaction notes

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