HCID 21488576, compound → HCID 21488579, compound

HRID 1974074Notes

Reaction equation

HRID 1974074 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]2[C:11](=[CH:12][CH:13]=1)[N:10]1[C:14](C)=[N:15][N:16]=[C:9]1[CH:8]=[C:7]2[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)([O-:3])=[O:2].I([O-])(=O)(=O)=[O:25].[Na+]>[Ru](=O)=O>[N+:1]([C:4]1[CH:13]=[CH:12][C:11]([N:10]2[CH:14]=[N:15][N:16]=[C:9]2[CH3:8])=[C:6]([CH:5]=1)[C:7]([C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)=[O:25])([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 21488576HCID 21488576, compoundHCID 23667635Sodium periodate

Product 1

HCID 21488579HCID 21488579, compound

Reagents, catalysts & solvents 1

HCID 82848Ruthenium dioxideCatalyst

Procedure

In the manner given in Example 3, 7-nitro-1-methyl-5-phenyl-s-triazolo[4,3-a]quinoline is oxidized at low temperature with sodium periodate and ruthenium dioxide to give 5-nitro-2-(3-methyl- 4H-1,2,4-triazol-4-yl)-benzophenone.

Sources & evidence

ORD record
ord-e06dcb05b6b34767a7aef416403d1580
Source dataset
uspto-grants-1976_12
Patent number
US04000151

Reaction notes

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