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HRID1974186

反应详情

EQUATION

反应方程式

HRID 1974186 的结构方程式

REACTANTS

反应物

2
结构：[BH4-].[Na+]
HCID4311764

Sodium borohydride (Na(BH4))

H4BNa

结构：COC(=O)[C@@H]1NC(=O)[C@@H]1N=[N+]=[N-]
HCID13566680

Methyl (2R,3R)-3-azido-4-oxoazetidine-2-carboxylate

C5H6N4O3

PRODUCTS

生成物

1
结构：[N-]=[N+]=N[C@H]1C(=O)N[C@H]1CO
HCID86734333

未命名化合物

PROCEDURE

实验过程

Methyl cis-3-azido-4-oxoazetidine-2-carboxylate was reduced with sodium borohydride as described in Preparation 3 and the product was chromatographed on silica gel with ethyl acetate as eluant to give cis-3-azido-2-hydroxymethyl-4-oxoazetidine.

WORKUP

后处理

  1. customas described in Preparation 3
  2. customthe product was chromatographed on silica gel with ethyl acetate as eluant