Huagongshe화공사 화학 정보 인쇄 보고서 · 연구 참고용
HRID 1974248생성일: 2026년 10월 26일
Diethyl Ether → S-(alpha-Ethyl-alpha-methylbenzylthio)methyl O,O-Diethyl Phosphorodithioate
https://huagongshe.com/reaction/1974248
참여 물질
| 역할 | 이름 | HCID | 투입량 |
|---|
| 반응물 | Diethyl Ether | HCID 3283 | — |
| 반응물 | O,O-Diethyl dithiophosphate | HCID 9274 | — |
| 반응물 | Phosphorodithioate | HCID 177047 | — |
| 반응물 | {2-[(Chloromethyl)sulfanyl]butan-2-yl}benzene | HCID 21489068 | — |
| 용매 | Triethylamine | HCID 8471 | — |
| 생성물 | S-(alpha-Ethyl-alpha-methylbenzylthio)methyl O,O-Diethyl Phosphorodithioate | HCID 21489063 | — |
반응 단계
To 0.091 mole of chloromethyl α-ethyl-α-methylbenzyl sulfide and 16.9 grams (0.091 mole) of the phosphorodithioate of the formula (C2H5O)2PSSH in 100 ml. of ether is added 9.2 grams of triethylamine, dropwise, maintaining the temperature at 25° C. The mixture is stirred for several hours and then washed with water and 5% sodium hydroxide solution. Evaporation of the solvent from the dried (magnesium sulfate) solution gives 31.3 grams (95%) of a colorless liqiuid. This material is chromatographically purified on a silica gel dry-column using 10 volume percent methylene chloride in hexane as the eluant.
출처 및 근거
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 특허 번호 | US04000269 |
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| 출처 데이터셋 | uspto-grants-1976_12 |
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| ORD ID | ord-217eb2fe4acb4827a7561177655b787a |
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| 출처 메모 | uspto-grants-1976_12 |
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