HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diphenyl disulfide → [(Tridecafluorohexyl)sulfanyl]benzene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diphenyl disulfide | HCID 13436 | — |
| Reactant | 1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluoro-6-iodohexane | HCID 67733 | — |
| Reactant | Sodium Formaldehyde Sulfoxylate | HCID 23689980 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | [(Tridecafluorohexyl)sulfanyl]benzene | HCID 13213429 | 40% |
Reaction Steps
Perfluorohexyl iodide (4.5 g), sodium hydroxymethanesulphinate (4 g) and phenyl disulphide (2.2 g) in dimethylformamide (10 cc) and water (0.5 cc) are stirred for 12 hours. After the usual treatment, phenyl perfluorohexyl sulphide is obtained in 40% yield.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05283337 |
| Source dataset | uspto-grants-1994_02 |
| ORD ID | ord-ad3d7b28c6384f92887b21eb32467a16 |
| Source note | uspto-grants-1994_02 |