HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → Naphthalene, 2-methoxy-6-(1-methylethenyl)-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | alpha,alpha-Dimethyl-6-methoxy-2-naphthalenemethanol | HCID 3511501 | — |
| Solvent | Hexamethylphosphoramide | HCID 12679 | — |
| Product | Naphthalene, 2-methoxy-6-(1-methylethenyl)- | HCID 5084230 | — |
Reaction Steps
A solution of 1.22 g 2-methoxy-6-(1-hydroxy-1-methylethyl)naphthalene in 25 ml hexamethylphosphoramide (HMPA) was heated to 240° C. for 15 minutes. The solution was cooled, poured into water, and the brown solid which had formed was filtered off and washed with isopropanol. Recrystallization of the brown solid from isopropanol gave 2-methoxy-6-isopropenylnaphthalene, mp 101° to 103 5° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05286902 |
| Source dataset | uspto-grants-1994_02 |
| ORD ID | ord-6824d5519564485ab74a9a4ac74c1eea |
| Source note | uspto-grants-1994_02 |