Benzoyl Peroxide → HCID 54442921, compound

HRID 1975826Notes

Reaction equation

HRID 1975826 reaction equation
[C:1]([O:9][C:10]1[CH:15]=[CH:14][C:13]([CH3:16])=[CH:12][C:11]=1[O:17][CH3:18])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1.[Br:37]N1C(=O)CCC1=O>>[C:1]([O:9][C:10]1[CH:15]=[CH:14][C:13]([CH2:16][Br:37])=[CH:12][C:11]=1[O:17][CH3:18])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 3

HCID 7187Benzoyl PeroxideHCID 67184N-bromobutanimideHCID 54266533HCID 54266533, compound

Product 1

HCID 54442921HCID 54442921, compound

Procedure

The synthesis of this compound proceeded in the same fashion as in Example 2 using 22.59 g (0.093 mol) of 2-methoxy-4-methylphenyl benzoate, a catalytic amount of benzoyl peroxide and 19.92 g (0.11 mol) of N-bromosuccinimide. The crude product (29.36 g) was purified by HPLC to give 8.95 g, m.p. 86°-88° C.

Workup

  1. customThe synthesis of this compound
  2. customThe crude product (29.36 g) was purified by HPLC
  3. customto give 8.95 g, m.p. 86°-88° C.

Sources & evidence

ORD record
ord-90458729451c4a14b6ba868de51532cd
Source dataset
uspto-grants-1994_02
Patent number
US05288871

Reaction notes

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