Trichloromelamine → HCID 54343372, compound

HRID 1975835Notes

Reaction equation

HRID 1975835 reaction equation
Cl[NH:2][C:3]1[N:8]=[C:7]([NH:9]Cl)[N:6]=[C:5]([NH:11]Cl)[N:4]=1.[Cl:13][CH2:14][CH2:15][C:16](Cl)=[O:17]>C(Cl)(Cl)(Cl)Cl.CCCCCC>[Cl:13][CH2:14][CH2:15][C:16]([NH:2][C:3]1[N:8]=[C:7]([NH:9][C:16](=[O:17])[CH2:15][CH2:14][Cl:13])[N:6]=[C:5]([NH:11][C:16](=[O:17])[CH2:15][CH2:14][Cl:13])[N:4]=1)=[O:17]

Participants

5

Reactant 2

HCID 24322TrichloromelamineHCID 693643-Chloropropionyl chloride

Product 1

HCID 54343372HCID 54343372, compoundYield 98%

Reagents, catalysts & solvents 2

HCID 5943Carbon TetrachlorideSolventHCID 8058HexaneSolvent

Procedure

To a stirring suspension of 2.3 g trichloromelamine in 40 ml CCl4 was added 7.62 g 3-chloropropionyl chloride under Argon. The reaction mixture was heated in an oil bath at 65°-70° C. for 6 hours. The reaction mixture was cooled and then diluted with 50 ml hexane. The precipitates were filtered, washed with hexane and dried under reduced pressure (3.9 g; 98% yield). The product thus obtained was characterized to be N'N',N"-tris (3-chloropropionyl) melamine by 1H NMR, 13C NMR, IR, and mass spectroscopy.

Workup

  1. temperatureThe reaction mixture was heated in an oil bath at 65°-70° C. for 6 hours
  2. temperatureThe reaction mixture was cooled
  3. filtrationThe precipitates were filtered
  4. washwashed with hexane
  5. customdried under reduced pressure (3.9 g; 98% yield)
  6. customThe product thus obtained

Sources & evidence

ORD record
ord-06475150cafc4c8b861695712d2e2998
Source dataset
uspto-grants-1994_02
Patent number
US05288865

Reaction notes

Loading…