HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl 5-bromothiophene-2-carboxylate → HCID 22000312, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl 5-bromothiophene-2-carboxylate | HCID 605713 | — |
| Reactant | 7-(1-Adamantyl)-6-benzyloxy-2-naphthylboronic acid | HCID 22000313 | — |
| Product | HCID 22000312 | HCID 22000312 | 67.4% |
Reaction Steps
Following the procedure of Example 1(c), but reacting 1.5 g (3.6 mmol) of 7-(1-adamantyl)-6-benzyloxy-2-naphthylboronic acid with 400 mg (1.8 mmol) of methyl 5-bromo-2-thiophenecarboxylate, 600 mg (65%) of the expected compound were obtained, which compound had a melting point of 170°-1° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06225328B1 |
| Source dataset | uspto-grants-2001_05 |
| ORD ID | ord-1d41081d4f4a4b33a24dcd2a508dae29 |
| Source note | uspto-grants-2001_05 |