Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Benzhydrol | HCID 7037 | — |
| Reactant | (Trifluoromethyl)benzene | HCID 7368 | — |
| Reactant | N-Hydroxyphthalimide | HCID 10665 | — |
| Reactant | p-Menth-1-ene | HCID 21671 | — |
| Reactant | Hexafluoroacetone trihydrate | HCID 36719 | — |
| Catalyst | Cobalt diacetate | HCID 6277 | — |
| Product | p-Menth-1-ene oxide | HCID 524011 | 42% |
Reaction Steps
A mixture of 3mmol of 1-p-menthene, 15mmol of benzhydrol, 0.3 mmol of N-hydroxyphthalimide, 0.0015 mmol of cobalt (II) acetate, 0.3 mmol of hexafluoroacetone trihydrate, and 3 ml of trifluoromethylbenzene was stirred at 60° C. under an oxygen atmosphere (1 atm) for 12 hours. Gas chromatographic analysis of products in a reaction mixture revealed that 1-p-menthene was converted, at a rate of 63%, into 1-p-menthene oxide (yield: 42%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06229023B1 |
|---|
| Source dataset | uspto-grants-2001_05 |
|---|
| ORD ID | ord-7e136347c7ac4d679d9651a9b3beb389 |
|---|
| Source note | uspto-grants-2001_05 |
|---|
