HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cyclohexanol → 5-Methyloxepan-2-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cyclohexanol | HCID 7966 | — |
| Reactant | Cyclohexanone | HCID 7967 | — |
| Reactant | 4-Methylcyclohexanol | HCID 11524 | — |
| Reactant | 4-Methylcyclohexanone | HCID 11525 | — |
| Product | 5-Methyloxepan-2-one | HCID 11116085 | 45.6% |
Reaction Steps
The procedure of Example 25 was repeated, except that 4-methylcyclohexanone (2 mmol) and 4-methylcyclohexanol (20 mmol) were respectively used in stead of cyclohexanone and cyclohexanol. As a result, γ-methyl-ε-caprolactone was formed in yield of 45.6% (on 4-methylcyclohexanone basis).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06229023B1 |
| Source dataset | uspto-grants-2001_05 |
| ORD ID | ord-e9be06758656493f86556ad392cedec9 |
| Source note | uspto-grants-2001_05 |