Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Allyl bromide | HCID 7841 | — |
| Reactant | Potassium Carbonate | HCID 11430 | — |
| Reactant | Methyl 4'-hydroxy(1,1'-biphenyl)-4-carboxylate | HCID 1490289 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 22625454 | HCID 22625454 | — |
Reaction Steps
A solution of methyl 4-(4′-hydroxyphenyl)benzoate (5 g) in N,N-dimethylformamide (50 ml) was treated with potassium carbonate (6.06 g) and allyl bromide (2.46 ml), then heated at 60° C. for 3 hours. After cooling, the reaction mixture was poured into ice-water (˜200 ml) and the resulting precipitate was collected by filtration, washed with water, then isopropyl ether, then dried to give methyl 4-[4′-(allyloxy) phenyl]benzoate (5.55 g) as a solid.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06232290B1 |
|---|
| Source dataset | uspto-grants-2001_05 |
|---|
| ORD ID | ord-95ce5e345dc24590b462413bf6678680 |
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| Source note | uspto-grants-2001_05 |
|---|
