HuagongsheHuagongshe Chemistry Print Report · For research reference only
m-Chloroperbenzoic acid → 1H-Pyrrole-2,5-dione, 1-[4-(oxiranylmethoxy)phenyl]-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | m-Chloroperbenzoic acid | HCID 70297 | — |
| Reactant | 1-{4-[(Prop-2-en-1-yl)oxy]phenyl}-1H-pyrrole-2,5-dione | HCID 13906801 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 1H-Pyrrole-2,5-dione, 1-[4-(oxiranylmethoxy)phenyl]- | HCID 21998062 | — |
Reaction Steps
N-(4-Allyloxyphenyl)maleimide (175 g, 76.4 mole) and 3-chloroperoxybenzoic acid (262 g, 70-75%, Across) were dissolved in 2.0 l of dichloromethane. After stirring for 72 h at room temperature, the reaction mixture was concentrated under reduced pressure to a slurry. Ether (2.0 l) was added to the slurry and stirred for 0.5 h at room temperature. The product was filtered off, washed with ether, and dried in an oven.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06232430B1 |
| Source dataset | uspto-grants-2001_05 |
| ORD ID | ord-b03691d5c32b43289936aaa6f109fb38 |
| Source note | uspto-grants-2001_05 |