HCID 12736684, compound → HCID 21995325, compound

HRID 1977681Notes

Reaction equation

HRID 1977681 reaction equation
[CH3:1][O:2][C:3]1[CH:4]=[C:5]([NH:13][C:14]2[N:19]=[C:18]([NH:20][C:21]3[CH:26]=[CH:25][CH:24]=[C:23]([O:27][CH3:28])[CH:22]=3)[CH:17]=[CH:16][N:15]=2)[CH:6]=[C:7](SC)[C:8]=1[O:9][CH3:10].[Cl:29]C1C=C([N+]([O-])=O)C=C(OC)C=1OC>>[ClH:29].[Cl:29][C:7]1[CH:6]=[C:5]([NH:13][C:14]2[N:19]=[C:18]([NH:20][C:21]3[CH:26]=[CH:25][CH:24]=[C:23]([O:27][CH3:28])[CH:22]=3)[CH:17]=[CH:16][N:15]=2)[CH:4]=[C:3]([O:2][CH3:1])[C:8]=1[O:9][CH3:10]

Participants

3

Reactant 2

HCID 12736684HCID 12736684, compoundHCID 21995320HCID 21995320, compound

Product 1

HCID 21995325HCID 21995325, compound

Procedure

The aniline starting material was prepared in a similar manner to the analogous aniline of Example 113, from 1-chloro-2,3-dimethoxy-5-nitrobenzene (1.08 g, 5.82 mmol), to give the desired product (0.85 g) as a white solid m.p. 66-68°. MS m/z 188 (M+H)+.

Sources & evidence

ORD record
ord-ea0ab1d93d9b454797f8e8de3577c5c5
Source dataset
uspto-grants-2001_05
Patent number
US06235746B1

Reaction notes

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