HuagongsheHuagongshe Chemistry Print Report · For research reference only
Samarium(III) iodide → HCID 22462010, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Samarium(III) iodide | HCID 10230237 | — |
| Reactant | Isopropenyl acrylate | HCID 11170937 | — |
| Reactant | 5-Hydroxy-1,3-adamantanedicarboxylic acid | HCID 12010644 | — |
| Solvent | 1,4-Dioxane | HCID 31275 | — |
| Product | HCID 22462010 | HCID 22462010 | 82% |
Reaction Steps
To 2 mL of dioxane were added 1.00 mmol of 1,3-dicarboxy-5-adamantanol, 0.10 mmol of samarium iodide (SmI2), 2.20 mmol of isopropenyl acrylate, and the resultant mixture was stirred at a temperature of 50° C. for 4 hours. The analysis by gas chromatography showed the formation of a 1,3-dicarboxy-5-acryloyloxyadamantane (yield: 82%, white solid) in the reaction mixture.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US06235851B1 |
| Source dataset | uspto-grants-2001_05 |
| ORD ID | ord-3fefa22a870d406898fc637362701b0e |
| Source note | uspto-grants-2001_05 |