1-Acetyl-3,5-dihyroxyadamantane → 1-Acetyl-3-hydroxy-5-acryloyloxyadamantane

HRID 1978122Notes

Reaction equation

HRID 1978122 reaction equation
[C:1](OCC12CC3CC(CC(O)(C3)C1)C2)(=[O:4])[CH:2]=[CH2:3].[C:18]([C:21]12[CH2:30][C:25]3([OH:31])[CH2:26][CH:27]([CH2:29][C:23]([OH:32])([CH2:24]3)[CH2:22]1)[CH2:28]2)(=[O:20])[CH3:19]>>[C:18]([C:21]12[CH2:22][C:23]3([O:32][C:1](=[O:4])[CH:2]=[CH2:3])[CH2:29][CH:27]([CH2:26][C:25]([OH:31])([CH2:24]3)[CH2:30]1)[CH2:28]2)(=[O:20])[CH3:19]

Participants

3

Reactant 2

HCID 121131431-Acetyl-3,5-dihyroxyadamantaneHCID 219967831-Hydroxy-3-(acryloyloxymethyl)adamantane

Product 1

HCID 219967871-Acetyl-3-hydroxy-5-acryloyloxyadamantaneYield 84%

Procedure

The reaction was conducted in the same manner as said (2) except that 1-acetyl-3,5-dihyroxyadamantane was used instead of the 1-acetyl-3-hydroxyadamantane, and, as a result, a 1-acetyl-3-hydroxy-5-acryloyloxyadamantane (yield: 84%, white solid) was obtained.

Sources & evidence

ORD record
ord-8df5e26718a24c60a8159d0c720cadcd
Source dataset
uspto-grants-2001_05
Patent number
US06235851B1

Reaction notes

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