1-Hydroxy-3-(acryloyloxymethyl)adamantane → HCID 21996795, compound

HRID 1978125Notes

Reaction equation

HRID 1978125 reaction equation
[C:1](OCC12CC3CC(CC(O)(C3)C1)C2)(=[O:4])[CH:2]=[CH2:3].[OH:18][C:19]12[CH2:28][CH:23]3[CH2:24][CH:25]([CH2:27][C:21]([OH:30])([C:22]3=[O:29])[CH2:20]1)[CH2:26]2>>[C:1]([O:18][C:19]12[CH2:28][CH:23]3[CH2:24][CH:25]([CH2:27][C:21]([OH:30])([C:22]3=[O:29])[CH2:20]1)[CH2:26]2)(=[O:4])[CH:2]=[CH2:3]

Participants

3

Reactant 2

HCID 219967831-Hydroxy-3-(acryloyloxymethyl)adamantaneHCID 22650053HCID 22650053, compound

Product 1

HCID 21996795HCID 21996795, compoundYield 87%

Procedure

The reaction was conducted in the same manner as said (2) except that 1,3-dihydroxyadamantane-4-one was used instead of the 1-hydroxyadamantane-2-one, and, as a result, a 1-acryloyloxy-3-hydroxyadamantane-4-one (yield: 87%, white solid) was produced.

Sources & evidence

ORD record
ord-cb260a59faf24f4d8bd5a9c72a396d70
Source dataset
uspto-grants-2001_05
Patent number
US06235851B1

Reaction notes

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