3,5-Dimethyl-1-adamantanol → 1,3-Dimethyl-5-acryloyloxyadamantane

HRID 1978127Notes

Reaction equation

HRID 1978127 reaction equation
[C:1](OCC12CC3CC(CC(O)(C3)C1)C2)(=[O:4])[CH:2]=[CH2:3].[CH3:18][C:19]12[CH2:28][C:23]3([OH:29])[CH2:24][CH:25]([CH2:27][C:21]([CH3:30])([CH2:22]3)[CH2:20]1)[CH2:26]2>>[CH3:18][C:19]12[CH2:28][C:23]3([O:29][C:1](=[O:4])[CH:2]=[CH2:3])[CH2:24][CH:25]([CH2:27][C:21]([CH3:30])([CH2:22]3)[CH2:20]1)[CH2:26]2

Participants

3

Reactant 2

HCID 2657933,5-Dimethyl-1-adamantanolHCID 219967831-Hydroxy-3-(acryloyloxymethyl)adamantane

Product 1

HCID 219968011,3-Dimethyl-5-acryloyloxyadamantaneYield 96%

Procedure

The reaction was conducted in the same manner as said (2) except that 1,3-dimethyl-5-hydroxyadamantane was used instead of the 1,3-dimethyl-5,7-dihydroxyadamantane, and, as a result, a 1,3-dimethyl-5-acryloyloxyadamantane (yield: 96%, colorless liquid) was produced.

Sources & evidence

ORD record
ord-09c0ebb88e2b4695b10fdd25585b1c6a
Source dataset
uspto-grants-2001_05
Patent number
US06235851B1

Reaction notes

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