Water → HCID 54010426, compound

HRID 1979128Notes

Reaction equation

HRID 1979128 reaction equation
[O-]S(C(F)(F)F)(=O)=O.[Na+].[CH2:10]=[CH:11][C:12](=[CH2:14])[CH3:13].[C:15]([O:18][CH:19]=[CH2:20])(=[O:17])[CH3:16].O>CO>[C:15]([O:18][CH:19]=[CH:20][CH2:13][CH:12]([CH3:14])[CH:11]=[CH2:10])(=[O:17])[CH3:16]

Participants

6

Reactant 4

HCID 962WaterHCID 6557IsopreneHCID 7904Vinyl AcetateHCID 23676748Sodium trifluoromethanesulfonate

Product 1

HCID 54010426HCID 54010426, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Conditions

Temperature
100 °C

Procedure

(p-Cymene)ruthenium dichloride dimer (27.8 mg, 0.091 mmol Ru) and sodium triflate (80 mg, 0.464 mmol) were dissolved in 10 ml of methanol. To the mixed solution were added isoprene (3 ml) and vinyl acetate (5 ml) and the mixture was stirred under heat at 100° C. for 14 hours. The resulting product was poured into water and extracted using toluene and the extract was subjected to a GLC analysis. As a result, it was confirmed that a co-dimer was produced with the conversion rate being 10% and the ratio of an isomer being 17:3.

Workup

  1. extractionextracted
  2. customwas produced with the conversion rate

Sources & evidence

ORD record
ord-65fec7253f1f45c6a9053ab81f9262c4
Source dataset
uspto-grants-2001_05
Patent number
US06239324B1

Reaction notes

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