Dichloromethane → N-Methyl-N-(2-methyl-1,3-dichloro-2-propanesulfenyl)carbamoyl fluoride

HRID 1980105Notes

Reaction equation

HRID 1980105 reaction equation
[CH2:1]([Cl:5])[C:2](=[CH2:4])[CH3:3].[CH3:6][N:7]([S:11]Cl)[C:8]([F:10])=[O:9].C(Cl)[Cl:14]>>[CH3:6][N:7]([S:11][C:2]([CH3:3])([CH2:4][Cl:14])[CH2:1][Cl:5])[C:8]([F:10])=[O:9]

Participants

4

Reactant 3

HCID 6344DichloromethaneHCID 112413-Chloro-2-methyl-1-propeneHCID 12922862N-chlorothio(methyl)carbamoyl fluoride

Product 1

HCID 54204012N-Methyl-N-(2-methyl-1,3-dichloro-2-propanesulfenyl)carbamoyl fluoride

Procedure

To a solution of 1.35 g of methallyl chloride in 25 ml of methylene chloride was added 2.15 g of N-methyl-N-chlorosulfenyl carbamoyl fluoride. The solution was heated to reflux for 45 min. and concentrated to 1.68 g of pale yellow oil.

Workup

  1. temperatureThe solution was heated
  2. temperatureto reflux for 45 min.
  3. concentrationconcentrated to 1.68 g of pale yellow oil

Sources & evidence

ORD record
ord-0873c4f0c90e4213ae58691c4b785273
Source dataset
uspto-grants-1984_11
Patent number
US04485113

Reaction notes

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