HuagongsheHuagongshe Chemistry Print Report · For research reference only
Diethyl Ether → 2-Methyl-3,4,5-trichloroisothiazolium hexafluorophosphate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Diethyl Ether | HCID 3283 | — |
| Reactant | Hexafluorophosphate | HCID 9886 | — |
| Reactant | Trichloroisothiazole | HCID 12333154 | — |
| Product | 2-Methyl-3,4,5-trichloroisothiazolium hexafluorophosphate | HCID 12889024 | 61% |
Reaction Steps
Trichloroisothiazole (15 ml) and 6.2 g (0.03 mol) of trimethyloxomium hexafluorophosphate were heated at 90° for 1 hr under nitrogen. After cooling, ether (100 ml) was added and the solid collected to yield 6.3 g (61%) of product, mp >240. Spectral data (NMR & IR) were consistent with the assigned structure.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04508908 |
| Source dataset | uspto-grants-1985_04 |
| ORD ID | ord-ee880016c217402b8489c18c85626629 |
| Source note | uspto-grants-1985_04 |