HuagongsheHuagongshe Chemistry Print Report · For research reference only
Methyl fluorosulfate → 3,4-Dichloro-2-methyl-5-ethoxycarbonylisothiazolium fluorosulfonate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Methyl fluorosulfate | HCID 9870 | — |
| Reactant | Ethyl 3,4-dichloro-1,2-thiazole-5-carboxylate | HCID 12889011 | — |
| Product | 3,4-Dichloro-2-methyl-5-ethoxycarbonylisothiazolium fluorosulfonate | HCID 12889013 | 99% |
Reaction Steps
3,4-Dichloro-5-ethoxycarbonylisothiazole (6.0 g, 0.027 mol) and 4 ml of methyl fluorosulfonate were heated at 110° for 1 hr under a nitrogen atmosphere. The solid was washed with ether and benzene to yield 9.0 g (99%) of 3,4-dichloro-2-methyl-5-ethoxycarbonylisothiazolium fluorosulfonate, mp 118-123. Analysis-calcuated for C7H8Cl2FNO5S2 : Cl, 20.84; N, 4.12; S, 18.85. Found Cl, 20.56; N, 4.06; S, 18.89.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04508908 |
| Source dataset | uspto-grants-1985_04 |
| ORD ID | ord-fa6e04e1eee048baa06eee7c6926691b |
| Source note | uspto-grants-1985_04 |