HuagongsheHuagongshe Chemistry Print Report · For research reference only
Vinyl isobutyl ether → N-[2-(1-isobutoxyethyl)ethyl]dithiocarbamic acid methyl ester
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Vinyl isobutyl ether | HCID 7992 | — |
| Reactant | p-Toluenesulfonic acid monohydrate | HCID 521998 | — |
| Reactant | Methyl (2-hydroxyethyl)carbamodithioate | HCID 13277332 | — |
| Solvent | Triethylamine | HCID 8471 | — |
| Product | N-[2-(1-isobutoxyethyl)ethyl]dithiocarbamic acid methyl ester | HCID 54402436 | 95% |
Reaction Steps
To a mixture of N-(2-hydroxyethyl)dithiocarbamic acid methyl ester (1.513 g) and isobutoxyethylene (2.59 ml) is added toluene-p-sulfonic acid monohydrate (9.5 mg). After stirring for 30 minutes, triethylamine (8 μl) is added to the mixture, and the resulting solution is concentrated under reduced pressure to give N-[2-(1-isobutoxyethyl)ethyl]dithiocarbamic acid methyl ester (3.2 g). Yield: 95%.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04508909 |
| Source dataset | uspto-grants-1985_04 |
| ORD ID | ord-264f82d276034acc95e1fe34235fe07c |
| Source note | uspto-grants-1985_04 |