Sodium Carbonate → HCID 13105344, compound

HRID 1981217Notes

Reaction equation

[OH:1][CH:2]([CH:10]([S:19]([C:22]1[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1)(=[O:21])=[O:20])[CH2:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)[CH2:3][CH2:4][CH2:5][C:6]([O:8]C)=[O:7].C(=O)([O-])[O-].[Na+].[Na+]>>[OH:1][CH:2]([CH:10]([S:19]([C:22]1[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=1)(=[O:21])=[O:20])[CH2:11][CH2:12][C:13]1[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=1)[CH2:3][CH2:4][CH2:5][C:6]([OH:8])=[O:7]

Participants

Reactant 2

HCID 10340Sodium Carbonate

HCID 20400109HCID 20400109, compound

Product 1

HCID 13105344HCID 13105344, compound

Procedure

Methyl 5-hydroxy-8-phenyl-6-phenylsulphonyl-octanoate was hydrolysed with aqueous sodium carbonate as in the hydrolysis step of Example 16 to afford the title compound as a viscous oil.

Sources & evidence

ORD record: ord-7abf0077e181411882ea9d84369d6efc
Source dataset: uspto-grants-1985_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04513005

Reaction notes

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