HuagongsheHuagongshe Chemistry Print Report · For research reference only
1-Chloromethylnaphthalene → HCID 13105371, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1-Chloromethylnaphthalene | HCID 6845 | — |
| Reactant | Benzenesulfinic acid, sodium salt | HCID 2723840 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Dimethylformamide | HCID 6228 | — |
| Product | HCID 13105371 | HCID 13105371 | — |
Reaction Steps
A solution of 1-(chloromethyl)-naphthalene (17.6 g) in dimethyl formamide (20 ml) was added to a stirred suspension of sodium benzenesulphinate (16.4 g) in dimethyl formamide (80 ml). After 20 hours at room temperature the mixture was diluted with water and the white precipitate filtered. Recrystallisation from ethyl acetate-petroleum ether 60°-80° C. gave the title product, m.p. 89° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04513005 |
| Source dataset | uspto-grants-1985_04 |
| ORD ID | ord-6898d811db86404382c109e0e0f84ce6 |
| Source note | uspto-grants-1985_04 |