HuagongsheHuagongshe Chemistry Print Report · For research reference only
4'-Hydroxyacetophenone → (4-Hydroxyphenyl)(oxo)acetaldehyde--water (1/1)
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4'-Hydroxyacetophenone | HCID 7469 | — |
| Reactant | Selenium Dioxide | HCID 24007 | — |
| Product | (4-Hydroxyphenyl)(oxo)acetaldehyde--water (1/1) | HCID 23318533 | — |
Reaction Steps
In the same manner as above, selenium dioxide is reacted with 4-hydroxyacetophenone (VII) to obtain 4-hydroxyphenylglyoxal hydrate (VIII), which is reacted with diaminomaleonitrile (VI) to obtain a phenol derivative (IX), which is then reacted with a corresponding carboxylic acid chloride in the presence of pyridine to obtain the objective compound (I).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04592857 |
| Source dataset | uspto-grants-1986_06 |
| ORD ID | ord-cd2a63f33858457093ec445cc694abda |
| Source note | uspto-grants-1986_06 |