Sodium Iodide → HCID 12715979, compound

Participants

Reaction Conditions

Reaction Steps

In 80 ml of acetonitrile is dissolved 6 g of sodium iodide and, then, 5 g of cyclohexanecarbonyl chloride is added dropwise to the solution under ice-cooling. This mixture is stirred at 0° C. for 30 minutes. Then, insoluble matters are removed by filtration and the filtrate is concentrated under reduced pressure. To the residue is added 20 ml of petroleum ether and insoluble matters are removed by filtration and the filtrate is subjected to distillation under reduced pressure to obtain 5.0 g of cyclohexanecarbonyl iodide. Yield: 61%. B.p. 75°-80° C./5 mmHg [b.p. 103°-105° C./11 mmHg according to "Bull. Chem. Soc. Japan" 34, 480 (1961)].

Provenance & Evidence