Benzyl Chloride → Methyl 3-(benzyloxy)benzoate

Participants

Reaction Steps

A mixture of 1564 g. (10.2 mole) of methyl 3- hydroxybenzoate, 1407.6 g. (10.2 mole) potassium carbonate and 1285.2 g. (10.2 mole) benzyl chloride in 5 l. of acetone is heated at reflux for 22 hours. The reaction mixture is then cooled, filtered and the filtrate evaporated. The residue is crystallized in a small volume of pentane to give a quantitative yield of the title compound.

Provenance & Evidence