HuagongsheHuagongshe Chemistry Print Report · For research reference only
Carbon Tetrachloride → 2-Nitro-3-Methylbenzotrichloride
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Carbon Tetrachloride | HCID 5943 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | 1-(Bromomethyl)-3-methyl-2-nitrobenzene | HCID 12932435 | — |
| Catalyst | Tetraethylammonium Chloride | HCID 5946 | — |
| Solvent | Dichloromethane | HCID 6344 | — |
| Product | 2-Nitro-3-Methylbenzotrichloride | HCID 13573565 | 36% |
Reaction Steps
1.5 gms of 2-nitro-3-methyl benzyl bromide was mixed with 0.05 gms of tetraethyl ammonium chloride in 15 ml of methylene chloride and 10 ml of carbon tetrachloride. 20 ml of 50% sodium hydroxide was added and the mixture refluxed for about 3 hours. After completion of the reaction, the organic layer was separated, washed with water, and the product separated to give 36% yield as determined by GC-Mass spectral analysis.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04593144 |
| Source dataset | uspto-grants-1986_06 |
| ORD ID | ord-a37bb128ab504e858de531d9a4779775 |
| Source note | uspto-grants-1986_06 |