HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-[(3-Nitrophenoxy)methyl]-1,3-benzothiazole → HCID 13631156, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-[(3-Nitrophenoxy)methyl]-1,3-benzothiazole | HCID 13631155 | — |
| Catalyst | Iron | HCID 23925 | — |
| Solvent | Hydrochloric Acid | HCID 313 | — |
| Product | HCID 13631156 | HCID 13631156 | 90.7% |
Reaction Steps
To a suspension of 3-[(2-benzthiazolyl)methoxy]nitrobenzene (18.6 g) in ethanolic hydrochloric acid is added powdered iron. The reaction is stirred overnight at room temperature. After neutralization with saturated aqueous sodium bicarbonate, the mixture is extracted with methylene chloride (3X). The extract is dried over magnesium sulfate and concentrated to give 15.1 g (90% yield) of product. m.p. 117°-120° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04594425 |
| Source dataset | uspto-grants-1986_06 |
| ORD ID | ord-759973ecd8d94acb8de896b3d44a3f8b |
| Source note | uspto-grants-1986_06 |