HuagongsheHuagongshe Chemistry Print Report · For research reference only
Formic Acid → Pyromellitic Acid
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Formic Acid | HCID 284 | — |
| Reactant | 4-Chlorophthalic acid | HCID 6964 | — |
| Reactant | Trimellitic acid | HCID 10708 | — |
| Reactant | HCID 178418416 | HCID 178418416 | — |
| Solvent | Sodium Hydroxide | HCID 14798 | — |
| Product | Pyromellitic Acid | HCID 6961 | — |
| Product | HCID 20150713 | HCID 20150713 | — |
Reaction Steps
For example, when the photocarbonylation reaction is effected by dissolving 4-chlorophthalic acid in an aqueous solution of sodium hydroxide (4-6N) and blowing carbon monoxide into the solution at a temperature of 60°-80° C. under a pressure of 1-10 atm, the reaction product consists mainly of the desired trimellitic acid, and by-product is scarcely formed except a small amount of formic acid. The reaction for obtaining pyromellitic acid from 5-chlorotrimellitic acid proceeds similarly as above.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04595470 |
| Source dataset | uspto-grants-1986_06 |
| ORD ID | ord-1c0d9d65d6ae424288345847bfda524b |
| Source note | uspto-grants-1986_06 |