HuagongsheHuagongshe Chemistry Print Report · For research reference only
Piperonal → 3-(3,4-Methylenedioxyphenyl)-6-dimethylaminophthalide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Piperonal | HCID 8438 | — |
| Reactant | 3-(Dimethylamino)benzoic acid | HCID 66837 | — |
| Reactant | 3-(9-Ethyl-3-carbazolyl)-6-dimethylaminophthalide | HCID 13651732 | — |
| Solvent | Acetic Anhydride | HCID 7918 | — |
| Product | 3-(3,4-Methylenedioxyphenyl)-6-dimethylaminophthalide | HCID 13651733 | 6.1% |
Reaction Steps
Following a procedure similar to that described in Example 1, part A above, 7.5 g of 3,4-(methylenedioxy)benzaldehyde and 9.1 g of 3-dimethylaminobenzoic acid were interacted in acetic anhydride to obtain 0.9 g of 3-(3,4-methylenedioxyphenyl)-6-dimethylaminophthalide (Formula II: R=CH3 ; X=H; Y=1-[3,4-(OCH2O)C6H3 ]) a light yellow solid melting over the range 134°-143° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04595768 |
| Source dataset | uspto-grants-1986_06 |
| ORD ID | ord-ed6cc94c376e40f081c35897b183a98d |
| Source note | uspto-grants-1986_06 |